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Process for Reduction Chemistry of Basic Copper Chloride and Transition Metals
Adaugat pe 17/05/2019 10:35:14 de weishida

Copper Chloride
and reduction chemistry of transition metals is a
complex process. Cu and Cu2 are compared by observingredox properties that
involve precipitation and complex ion formation. A complex ionis an ion that
contains a metal cation connected to one or more small molecules or ions with
lone pairs of electrons. Forming a complex ion occurs in steps and each step has
its own characteristic equilibrium constant. In order to insure that
complexation is complete, significant excesses of ligand sneed to be added. The
reactions in the demonst ration by Ophardt compared and contrasted the relative
stabilities of the Cu and Cu2 Basic Copper Chloride states with different
ligands attached.

This behavior is different than most other transition metals
because very few of them have common states of both +1 and +2. Also, the larger
oxidation state of a transition metal often has the largest reduction potential
value, but for copper, the smaller oxidation state has the largest value. Iron
is one of a few transition metals that has common states of +2 and +3. The
transition of the +3 state to the +2 state has a much larger potential value
(+0.77 V)3than the value for the transition of the +2 state to the elemental

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Tag-uri: Basic Copper Chloride

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